TY - JOUR A1 - Ehrlich, Hermann A1 - Janussen, Dorte A1 - Simon, Paul A1 - Bazhenov, Vasily V. A1 - Shapkin, Nikolay P. A1 - Erler, Christiane A1 - Mertig, Michael A1 - Born, René A1 - Heinemann, Sascha A1 - Hanke, Thomas A1 - Worch, Hartmut A1 - Vournakis, John N. T1 - Nanostructural organization of naturally occurring composites - part II: silica-chitin-based biocomposites T2 - Journal of nanomaterials N2 - Investigations of the micro- and nanostructures and chemical composition of the sponge skeletons as examples for natural structural biocomposites are of fundamental scientific relevance. Recently, we show that some demosponges (Verongula gigantea, Aplysina sp.) and glass sponges (Farrea occa, Euplectella aspergillum) possess chitin as a component of their skeletons. The main practical approach we used for chitin isolation was based on alkali treatment of corresponding external layers of spicules sponge material with the aim of obtaining alkali-resistant compounds for detailed analysis. Here, we present a detailed study of the structural and physicochemical properties of spicules of the glass sponge Rossella fibulata. The structural similarity of chitin derived from this sponge to invertebrate alpha chitin has been confirmed by us unambiguously using physicochemical and biochemical methods. This is the first report of a silica-chitin composite biomaterial found in Rossella species. Finally, the present work includes a discussion related to strategies for the practical application of silica-chitin-based composites as biomaterials. Y1 - 2012 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/24622 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-246227 SN - 1687-4129 SN - 1687-4110 VL - 2008 IS - Article ID 670235 PB - Hindawi Publ. CY - New York, NY ER -