TY  - JOUR
A1  - Breunig, Jens Michael
A1  - Lerner, Hans-Wolfram
A1  - Bolte, Michael
T1  - A triclinic polymorph of bis-(μ-di-tert-butyl-phosphanido)bis-[(di-tert-butyl-phosphane)palladium(I)]
T2  - Acta crystallographica / Section E, Structure reports online
N2  - A new polymorph of the title compound, [Pd2(C8H18P)2(C8H19P)2], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992 [triangle]), J. Organo­met. Chem. 423, 263–270] crystallizes in the monoclinic C2/c space group. The title compound features a dinuclear palladium complex with a planar central Pd2(μ-P)2 core (r.m.s. deviation = 0.003 Å). The Pd—Pd distance of 2.5988 (5) Å is within the range of a PdI—PdI bond. The mol­ecules of both polymorphs are located on a crystallographic centre of inversion. The mol­ecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different.
Y1  - 2012
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/25858
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-258582
SN  - 1600-5368
VL  - 68
IS  - m836
PB  - Munksgaard
CY  - Copenhagen
ER  -