TY  - JOUR
A1  - Alfonso, Ignacio
A1  - Bolte, Michael
A1  - Burguete, M. Isabel
A1  - Luis, Santiago V.
T1  - Crystal structure of the N-benzyloxycarbonyl-Alanyl-Phenylalanyl-methyl ester: the importance of the H-bonding pattern
T2  - Crystals : open access journal
N2  - Large crystals of the methyl ester of the N-a-benzyloxycarbonyl protected Ala-Phe dipeptide (Z-AF-OMe) were obtained after the very slow evaporation of a solution of the corresponding carboxylic acid (Z-AF-OH) in methanol containing an excess of HCl. The structure was confirmed by single crystal X-ray diffraction data. It crystallizes in the orthorhombic space group P212121 with unit cell dimensions a = 5.0655(6) Å, b = 8.4614(8) Å, c = 46.856(5) Å, V = 2008.3(4) Å3, Z = 4. In the crystal, the molecules form hydrogen bonded chains running along the a axis of the unit cell. Other secondary interactions are also discussed.
KW  - peptides
KW  - alanylphenylalanyl derivative
KW  - crystal structure
KW  - hydrogen bond
Y1  - 2011
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/24584
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-245841
SN  - 2073-4352
VL  - 1
IS  - 3
SP  - 163
EP  - 170
PB  - Molecular Diversity Preservation International (MDPI)
CY  - Basel
ER  -