TY - JOUR A1 - Vitze, Hannes A1 - Lerner, Hans-Wolfram A1 - Bolte, Michael T1 - Sodium pentafluorophenylborate T2 - Acta crystallographica / Section E, Structure reports online N2 - The crystal structure of the title compound, Na[(C6F5)BH3], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na...B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na...F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH3 group. Y1 - 2012 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/27424 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-274244 SN - 1600-5368 N1 - Authors will not be asked to transfer copyright to the IUCr, but will instead be asked to agree during article submission to an open-access licence. This licence is identical to the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode. VL - 68 IS - m1371 PB - Munksgaard CY - Copenhagen ER -