TY - JOUR A1 - Sipilä, Mikko A1 - Lehtipalo, Katrianne A1 - Kulmala, Markku A1 - Petäjä, Tuukka A1 - Junninen, Heikki A1 - Aalto, Pasi A1 - Manninen, Hanna Elina A1 - Vartianinen, E. A1 - Riipinen, Ilona A1 - Kyrö, Ella-Maria A1 - Curtius, Joachim A1 - Kürten, Christoph Andreas A1 - Borrmann, Stephan A1 - O'Dowd, Colin D. T1 - Applicability of condensation particle counters to measure atmospheric clusters T2 - Atmospheric chemistry and physics. Discussions N2 - The ambient and laboratory molecular and ion clusters were investigated. Here we present data on the ambient concentrations of both charged and uncharged molecular clusters as well as the performance of a pulse height condensation particle counter (PH-CPC) and an expansion condensation particle counter (E-CPC). The ambient molecular cluster concentrations were measured using both instruments, and they were deployed in conjunction with ion spectrometers and other aerosol instruments in Hyytiälä, Finland at the SMEAR II station during 1 March to 30 June 2007. The observed cluster concentrations varied and were from ca. 1000 to 100 000 cm−3. Both instruments showed similar concentrations. The average size of detected clusters was approximately 1.8 nm. As the atmospheric measurements at sub 2-nm particles and molecular clusters are a challenging task, and we were most likely unable to detect the smallest clusters, the reported concentrations are our best estimates for minimum cluster concentrations in boreal forest environment. Y1 - 2008 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/29248 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-292485 SN - 1680-7367 SN - 1680-7375 N1 - © Author(s) 2008. This work is licensed under a Creative Commons License. VL - 8 SP - 4373 EP - 4405 PB - European Geosciences Union CY - Katlenburg-Lindau ER -