TY - JOUR A1 - Sipilä, Mikko A1 - Lehtipalo, Katrianne A1 - Junninen, Heikki A1 - Petäjä, Tuukka A1 - Kulmala, Markku A1 - Aalto, Pasi A1 - Manninen, Hanna Elina A1 - Kyrö, Ella-Maria A1 - Asmi, Eija A1 - Riipinen, Ilona A1 - Curtius, Joachim A1 - Kürten, Christoph Andreas A1 - Borrmann, Stephan A1 - O'Dowd, Colin D. T1 - Applicability of condensation particle counters to measure atmospheric clusters T2 - Atmospheric chemistry and physics N2 - This study presents an evaluation of a pulse height condensation particle counter (PH-CPC) and an expansion condensation particle counter (E-CPC) in terms of measuring ambient and laboratory-generated molecular and ion clusters. Ambient molecular cluster concentrations were measured with both instruments as they were deployed in conjunction with an ion spectrometer and other aerosol instruments in Hyytiälä, Finland at the SMEAR II station between 1 March and 30 June 2007. The observed cluster concentrations varied and ranged from some thousands to 100 000 cm -3. Both instruments showed similar (within a factor of ~5) concentrations. An average size of the detected clusters was approximately 1.8 nm. As the atmospheric measurement of sub 2-nm particles and molecular clusters is a challenging task, we conclude that most likely we were unable to detect the smallest clusters. Nevertheless, the reported concentrations are the best estimates to date for minimum cluster concentrations in a boreal forest environment. Y1 - 2008 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/5858 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30-58016 SN - 1680-7316 SN - 1680-7324 N1 - © Author(s) 2008. This work is distributed under the Creative Commons Attribution 3.0 License. VL - 8 SP - 4049 EP - 4060 PB - European Geosciences Union CY - Katlenburg-Lindau ER -