TY - JOUR A1 - Levin, Ingeborg A1 - Naegler, Tobias A1 - Heinz, Renate A1 - Osusko, Daniel A1 - Cuevas, Emilio A1 - Engel, Andreas A1 - Ilmberger, Johann A1 - Langenfelds, Ray L. A1 - Neininger, Bruno A1 - Rohden, Christoph von A1 - Steele, L. Paul A1 - Weller, Rolf A1 - Worthy, Douglas E. A1 - Zimov, Sergej A. T1 - Atmospheric observation-based global SF6 emissions - comparison of top-down and bottom-up estimates T2 - Atmospheric chemistry and physics. Discussions N2 - Emissions of sulphur hexafluoride (SF6), one of the strongest greenhouse gases on a per molecule basis, are targeted to be collectively reduced under the Kyoto Protocol. Because of its long atmospheric lifetime (≈3000 years), the accumulation of SF6 in the atmosphere is a direct measure of its global emissions. Examination of our extended data set of globally distributed high-precision SF6 observations shows an increase in SF6 abundance from near zero in the 1970s to a global mean of 6.7 ppt by the end of 2008. In-depth evaluation of our long-term data records shows that the global source of SF6 decreased after 1995, most likely due to SF6 emission reductions in industrialised countries, but increased again after 1998. By subtracting those emissions reported by Annex I countries to the United Nations Framework Convention of Climatic Change (UNFCCC) from our observation-inferred SF6 source leaves a surprisingly large gap of more than 70–80% of non-reported SF6 emissions in the last decade. Y1 - 2009 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/8121 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30-80693 UR - http://www.atmos-chem-phys-discuss.net/9/26653/2009/ SN - 1680-7375 SN - 1680-7367 N1 - Begutachteter Artikel erschienen in: Atmospheric chemistry and physics, 10.2010, Nr. 6, S. 2655-2662, doi:10.5194/acp-10-2655-2010 N1 - © Author(s) 2009. This work is distributed under the Creative Commons Attribution 3.0 License. VL - 9 SP - 26653 EP - 26672 PB - EGU CY - Katlenburg-Lindau ER -