TY  - JOUR
A1  - Zhuang, Jinliang
A1  - Friedel, Jasmin
A1  - Terfort, Andreas
T1  - The oriented and patterned growth of fluorescent metal–organic frameworks onto functionalized surfaces
T2  - Beilstein journal of nanotechnology
N2  - A metal–organic framework (MOF) material, [Zn2(adc)2(dabco)] (adc = anthracene-9,10-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]­octane), the fluorescence of which depends on the loading of its nanopores, was synthesized in two forms: as free-flowing nanocrystals with different shapes and as surface-attached MOFs (SURMOFs). For the latter, we used self-assembled monolayers (SAMs) bearing functional groups, such as carboxylate and pyridyl groups, capable of coordinating to the constituents of the MOF. It could be demonstrated that this directed coordination also orients the nanocrystals deposited at the surface. Using two different patterning methods, i.e., microcontact printing and electron-beam lithography, the lateral distribution of the functional groups could be determined in such a way that the highly localized deposition of the SURMOF films became possible.
KW  - electron-beam lithography
KW  - irradiation-promoted exchange reaction
KW  - microcontact printing
KW  - radiation-induced nanostructure
KW  - self-assembled monolayer
KW  - surface-attached metal–organic framework
Y1  - 2012
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/26345
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-263458
SN  - 2190-4286
N1  - This is an Open Access article under the terms of the
Creative Commons Attribution License
(http://creativecommons.org/licenses/by/2.0), which
permits unrestricted use, distribution, and reproduction in
any medium, provided the original work is properly cited
VL  - 3
SP  - 570
EP  - 578
PB  - Beilstein-Institut zur Förderung der Chemischen Wissenschaften
CY  - Frankfurt, M.
ER  -