TY  - JOUR
A1  - Lerner, Hans-Wolfram
A1  - Sänger, Inge
A1  - Polborn, Kurt
A1  - Bolte, Michael
A1  - Wagner, Matthias
T1  - Synthese der Amide M[N(SiMetBu2)(SitBu3)] (M = Li, Na) durch N2-Eliminierung aus den Triazeniden M[tBu3SiNNNSiMetBu2] (M = Li, Na)
T1  - Synthesis of the amides M[N(SiMetBu2)(SitBu3)] (M = Li, Na) by N2-elimination reaction of the triazenides M[tBu3SiNNNSiMetBu2] (M= Li, Na)
T2  - Zeitschrift für Naturforschung, B
N2  - The thermolabile triazenides M[tBu3SiNNNSiMetBu2] (M = Li, Na) are accessible from the reaction of tBu2MeSiN3 with the silanides MSitBu3 (M = Li, Na) at −78 °C in THF. At r. t. N2 elimination from the triazenides M[tBu3SiNNNSiMetBu2] (M = Li, Na) takes place with the formation of M[N(SiMetBu2)(SitBu3)] (M = Li, Na). X-Ray quality crystals of Li(THF)[N(SiMetBu2)(SitBu3)] (orthorhombic, Pna21) are obtained from a benzene solution at ambient temperature. In contrast to the structures of the unsolvated silanides MSitBu3 (M = Li, Na), the THF adduct Li(THF)3SitBu3 is monomeric in the solid state (orthorhombic, Pna21).
KW  - Triazene
KW  - Nitrogen
KW  - Silanide
KW  - Silyl Amine
KW  - X-Ray Structure Analysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/80414
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-804146
SN  - 1865-7117
SN  - 0932-0776
VL  - 62.2007
IS  - 10
SP  - 1285
EP  - 1290
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -