TY  - JOUR
A1  - Lerner, Hans-Wolfram
A1  - Sänger, Inge
A1  - Schödel, Frauke
A1  - Bolte, Michael
A1  - Wagner, Matthias
T1  - Untersuchungen zur Reaktivität des Lithiumphosphanids Li[PtBu2] gegenüber GaCl3
T1  - Investigations of the reactivity of the lithiumphosphanide Li[PtBu2] towards GaCl3
T2  - Zeitschrift für Naturforschung, B
N2  - Single crystals suitable for X-ray diffraction of (tBu2P)3Ga (monoclinic, space group Cc) were obtained from GaCl3 and two equivalents of Li[PtBu2] at room temperature in benzene. The phosphanylgallane (tBu2P)3Ga was also produced via a one-pot approach by reaction of GaCl3 with three or more than three equivalents of Li[PtBu2]. However, treatment of one equivalent of GaCl3 with one equivalent of Li[PtBu2] and subsequent protolysis yielded [tBu2PH2][tBu2P(GaCl3)2 - Li(Cl3Ga)2PtBu2]. Single crystals of this phosphonium salt (monoclinic, space group Cc) were obtained from benzene at room temperature.
KW  - Gallium
KW  - Phosphorus
KW  - Addition Compounds
KW  - X-Ray Structure Analysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/80956
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-809562
SN  - 1865-7117
SN  - 0932-0776
VL  - 66.2011
IS  - 7
SP  - 695
EP  - 699
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -