trans-Dichloridobis(triphenylphosphane-κP)palladium(II) benzene hemisolvate
The title complex, [PdCl2(C18H15P)2]·0.5C6H6, has the PdII ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh3 and Cl ligands mutually trans. The benzene solvent molecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenylphosphane)palladium(II) 1,4-dichlorobenzene sesquisolvate [Kitano et al. (1983 [triangle]). Acta Cryst. C39, 1015–1017].
| Author: | Frank Meyer-Wegner, Hans-Wolfram Lerner, Tanja Sinke, Michael Bolte |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-252327 |
| DOI: | http://dx.doi.org/10.1107/S1600536812012494 |
| ISSN: | 1600-5368 |
| Pubmed Id: | http://www.ncbi.nlm.nih.gov/pubmed?term=22589859 |
| Parent Title (English): | Acta crystallographica : Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Year of first Publication: | 2012 |
| Publishing Institution: | Univ.-Bibliothek Frankfurt am Main |
| Volume: | 68 |
| Issue: | m570 |
| Institutes: | Biochemie und Chemie |
| Dewey Decimal Classification: | 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Note: | Lizenz: http://journals.iucr.org/services/oa/openaccess_e.html |
| Licence (German): |  Creative Commons - Namensnennung 3.0 |
