Redetermination of (acetonitrile-κN)dicarbon-yl(η(5)-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate
The crystal structure of the title compound, [Fe(C5H5)(CH3CN)(CO)2]BF4, of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 [triangle]). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The FeII atom in the complex cation is coordinated by a cyclopentadienyl ring, two carbonyl ligands and an acetonitrile molecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF4 − anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site.
| Author: | Theresa Irene Kückmann, Hans-Wolfram Lerner, Michael Bolte |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-258600 |
| DOI: | http://dx.doi.org/10.1107/S1600536812027857 |
| ISSN: | 1600-5368 |
| Pubmed Id: | http://www.ncbi.nlm.nih.gov/pubmed?term=22807785 |
| Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 23.06.2012 |
| Date of first Publication: | 23.06.2012 |
| Publishing Institution: | Univ.-Bibliothek Frankfurt am Main |
| Volume: | 68 |
| Issue: | m966 |
| Institutes: | Biochemie und Chemie |
| Dewey Decimal Classification: | 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 3.0 |
