(Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ2 C 1,N]iridium(III)
The IrIII atom of the title compound, [Ir(C11H8N)2Cl(CH3CN)], displays a distorted octahedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C—Ir—Cl = 176.22 (9)°]. The pyridylphenyl groups only show a small deviation from planarity, with the dihedral angle between the planes of the two six-membered rings in each pyridylphenyl group being 5.6 (2) and 5.8 (1)°. The crystal packing shows intermolecular C—H[cdots, three dots, centered]Cl, C—H[cdots, three dots, centered]π(acetonitrile) and C—H[cdots, three dots, centered]π(pyridylphenyl) contacts.
Download full text files
e-67-m1837.pdf (538 KB)
Export metadata
Additional Services
| Author: | Florian Blasberg, Jan W. Bats, Matthias Wagner, Hans-Wolfram Lerner |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-263375 |
| DOI: | http://dx.doi.org/10.1107/S1600536811049373 |
| ISSN: | 1600-5368 |
| Pubmed Id: | http://www.ncbi.nlm.nih.gov/pubmed?term=22199613 |
| Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 25.11.2011 |
| Date of first Publication: | 25.11.2011 |
| Publishing Institution: | Univ.-Bibliothek Frankfurt am Main |
| Volume: | 67 |
| Issue: | m1837-m1838 |
| First Page: | m1837 |
| Last Page: | m1838 |
| Institutes: | Biochemie und Chemie |
| Dewey Decimal Classification: | 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Note: | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Licence (German): |  Creative Commons - Namensnennung 3.0 |
