(Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ2 C 1,N]iridium(III)

The IrIII atom of the title compound, [Ir(C11H8N)2Cl(CH3CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respe
The IrIII atom of the title compound, [Ir(C11H8N)2Cl(CH3CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C—Ir—Cl = 176.22 (9)°]. The pyridyl­phenyl groups only show a small deviation from planarity, with the dihedral angle between the planes of the two six-membered rings in each pyridyl­phenyl group being 5.6 (2) and 5.8 (1)°. The crystal packing shows inter­molecular C—H[cdots, three dots, centered]Cl, C—H[cdots, three dots, centered]π(acetonitrile) and C—H[cdots, three dots, centered]π(pyridyl­phen­yl) contacts.
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Metadaten
Author:Florian Blasberg, Jan W. Bats, Matthias Wagner, Hans-Wolfram Lerner
URN:urn:nbn:de:hebis:30:3-263375
DOI:http://dx.doi.org/10.1107/S1600536811049373
ISSN:1600-5368
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=22199613
Parent Title (English):Acta crystallographica / Section E, Structure reports online
Publisher:Munksgaard
Place of publication:Copenhagen
Document Type:Article
Language:English
Date of Publication (online):2011/11/25
Date of first Publication:2011/11/25
Publishing Institution:Univ.-Bibliothek Frankfurt am Main
Release Date:2012/09/18
Volume:67
Issue:m1837-m1838
First Page:m1837
Last Page:m1838
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 3.0

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