1-(Bromomercurio)ferrocene

The asymmetric unit of the title compound, [Fe(C5H5)(C5H4BrHg)], contains two independent molecules, A and B, in which the Hg-C bond lengths are 2.045 (6) and 2.046 (6) Å, the Hg-Br bond lengths are 2.4511 (9) and 2.4562
The asymmetric unit of the title compound, [Fe(C5H5)(C5H4BrHg)], contains two independent molecules, A and B, in which the Hg-C bond lengths are 2.045 (6) and 2.046 (6) Å, the Hg-Br bond lengths are 2.4511 (9) and 2.4562 (7) Å, and the C-Hg-Br angles are 176.42 (17) and 177.32 (17)°. The two cyclopentadienyl rings of mol-ecule A are eclipsed, while those of mol-ecule B are almost staggered. The HgBr groups are connected by intermolecular Hg⋯Br contacts of 3.3142 (9)-3.4895 (11) Å, forming layers parallel to (001). These layers contain both four-membered (HgBr)2 and eight-membered (HgBr)4 rings. Ferrocene-ferrocene C-H⋯π contacts connect the molecular layers along the c-axis direction. 
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Metadaten
Author:Jens Michael Breunig, Hans-Wolfram Lerner, Jan W. Bats
URN:urn:nbn:de:hebis:30:3-334130
DOI:http://dx.doi.org/10.1107/S1600536813032923
ISSN:1600-5368
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=24526943
Parent Title (English):Acta crystallographica / Section E, Structure reports online
Publisher:Munksgaard
Place of publication:Copenhagen
Document Type:Article
Language:English
Date of Publication (online):2013/12/11
Date of first Publication:2013/12/11
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2014/04/07
Volume:70
Issue:m13
Pagenumber:13
Note:
Copyright © Breunig et al. 2014. This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
HeBIS PPN:364446633
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 4.0

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