Crystal structure of 1,3-bis[(E)-4-methoxybenzylideneamino]propan-2-ol

The title Schiff base, C19H22N2O3, was synthesized via the condensation reaction of 1,3-di­amino­propan-2-ol with 4-meth­oxy­benzaldehyde using water as solvent. The mol­ecule exists in an E,E conformation with respect t
The title Schiff base, C19H22N2O3, was synthesized via the condensation reaction of 1,3-di­amino­propan-2-ol with 4-meth­oxy­benzaldehyde using water as solvent. The mol­ecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O-H...N hydrogen bonds link the mol­ecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C-H...O inter­actions and C-H...[pi] short contacts, forming a three-dimensional network.
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Metadaten
Author:Augusto Rivera, Ingrid Miranda-Carvajal, Jaime Ríos-Motta, Michael Bolte
URN:urn:nbn:de:hebis:30:3-428952
URL:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137596
DOI:http://dx.doi.org/10.1107/S2056989016016947
ISSN:2056-9890
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=27980818
Parent Title (English):Acta crystallographica. Section E, Crystallographic communications
Publisher:International Union of Crystallography
Place of publication:Chester
Contributor(s):W. T. A. Harrison
Document Type:Article
Language:English
Date of Publication (online):2017/02/23
Date of first Publication:2016/10/22
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2017/02/23
Tag:C-H...O inter­actions; Schiff bases; crystal structure; hydrogen bonding
Volume:72
Issue:Pt 12
Pagenumber:8
First Page:1731
Last Page:1733
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
HeBIS PPN:450967670
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 2.0

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