Crystal structure of the co-crystalline adduct 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]do­decane (TATD)–4-iodo­phenol (1/2) : supra­molecular assembly mediated by halogen and hydrogen bonding

The asymmetric unit of the title co-crystalline adduct, 1,3,6,8-tetra­aza­tri­cyclo[4.4.1.13,8]dodecane (TATD)–4-iodo­phenol (1/2), C8H16N4·2C6H5IO, comprises a half mol­ecule of the aminal cage polyamine plus a 4-iodo­p
The asymmetric unit of the title co-crystalline adduct, 1,3,6,8-tetra­aza­tri­cyclo[4.4.1.13,8]dodecane (TATD)–4-iodo­phenol (1/2), C8H16N4·2C6H5IO, comprises a half mol­ecule of the aminal cage polyamine plus a 4-iodo­phenol mol­ecule. A twofold rotation axis generates the other half of the adduct. The components are linked by two inter­molecular O—H⋯N hydrogen bonds. The adducts are further linked into a three-dimensional framework structure by a combination of N⋯I halogen bonds and weak non-conventional C—H⋯O and C—H⋯I hydrogen bonds.
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Metadaten
Author:Augusto Rivera, Jicli José Rojas, Jaime Ríos-Motta, Michael Bolte
URN:urn:nbn:de:hebis:30:3-429132
DOI:http://dx.doi.org/10.1107/S20569890170149
ISSN:2056-9890
Parent Title (German):Acta crystallographica. Section E, Crystallographic communications
Publisher:International Union of Crystallography
Place of publication:Chester
Contributor(s):J. Simpson
Document Type:Article
Language:English
Date of Publication (online):2017/11/16
Date of first Publication:2017/10/20
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2017/11/16
Tag:TATD; co-crystalline adduct; crystal structure; halogen bonding; hydrogen bonding
Volume:72
Issue:11
Pagenumber:8
First Page:1692
Last Page:1695
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
HeBIS PPN:425141020
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 2.0

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