Mechanochemical synthesis of a cocrystal of two supramolecular hydrogen-bonded aggregates of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane (tatu) with 4-tert-butylphenol bearing different hydrogen bonding interactions

The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is 
The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.
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Author:Augusto Rivera, Jicli José Rojas, Jaime Ríos-Motta, Michael Bolte
URN:urn:nbn:de:hebis:30:3-535725
DOI:http://dx.doi.org/10.3390/cryst8080309
ISSN:2073-4352
Parent Title (English):Crystals
Publisher:MDPI
Place of publication:Basel
Document Type:Article
Language:English
Date of Publication (online):2018/07/30
Date of first Publication:2018/07/30
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2020/06/17
Tag:aminal structure; cocrystals; crystal engineering; hydrogen bonds; noncovalent interactions; supramolecular chemistry
Volume:8
Issue:8, Art. 309
Pagenumber:8
First Page:1
Last Page:8
Note:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 4.0

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