Dibromidotris(dimethylamine)-magnesium(II)
The Mg centre in the title compound, [MgBr2(C2H7N)3], is pentacoordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethylamine ligands in equatorial positions. The MgII centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N-H...Br hydrogen bonds. The N atom and H atoms of one dimethylamine ligand are disordered over two equally occupied positions. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(N–C) = 0.005 A° ; disorder in main residue; R factor = 0.022; wR factor = 0.049; data-to-parameter ratio = 21.1.
| Author: | Hannes Vitze, Hans-Wolfram Lerner, Michael Bolte |
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| URN: | urn:nbn:de:hebis:30-68927 |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 02.09.2009 |
| Year of first Publication: | 2009 |
| Publishing Institution: | Univ.-Bibliothek Frankfurt am Main |
| Source: | Acta Cryst. (2009). E65, m888 [ doi:10.1107/S1600536809024702 ] |
| HeBIS PPN: | 217323758 |
| Institutes: | Biochemie und Chemie |
| Dewey Decimal Classification: | 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Note: | ISSN 1600-5368 ; Copyright © International Union of Crystallography ; This licence is identical to the Creative Commons Attribution Licence. http://journals.iucr.org/services/oa/openaccess_e.html |
| Licence (German): |  Veröffentlichungsvertrag für Publikationen ohne Print on Demand |
