Influence of environment on the photooxidation of tryptophan with the carcinogenic hydrocarbon 3,4-benzopyrene in aqueous solutions of soap, caffeine, and urea
- The solvent dependence of the photooxidation of tryptophan and 3,4-benzopyrene in aqueous solutions was studied by quantum yield measurements. When the hydrocarbon is dissolved in aqueous solution of caffeine, the quantum yields indicate a 3,4-benzopyrene photosensitized tryptophan oxidation instead of a photocooxidation, which is indicated in aqueous solution of sodium dodecylsulfate. The same photosensitized oxidation as in caffeine solution is observed, when urea ( 6 m) is added to the soap solution, while the fluorescence and absorption spectra indicate no change in the solvation state of the hydrocarbon, comparable to the change from hydrophobic solubilization by the detergent to dipole — induced dipole complex solubilization by caffeine. It is concluded that the difference in the reaction pathways is caused by different solvation states of the excited or reacting oxygen. In the discussion of the results it is referred to reactions of inhibitors.
Author: | Günter Reske, Horst Bauer |
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URN: | urn:nbn:de:hebis:30:3-740374 |
DOI: | https://doi.org/10.1515/znc-1973-7-806 |
ISSN: | 1865-7125 |
ISSN: | 0939-5075 |
Parent Title (German): | Zeitschrift für Naturforschung, C |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1973 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2023/12/29 |
Tag: | 3,4-Benzopyrene; photooxidation; tryptophan |
Volume: | 23.1973 |
Issue: | 7-8 |
Page Number: | 7 |
First Page: | 390 |
Last Page: | 396 |
HeBIS-PPN: | 517670127 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |