Untersuchungen zur Charakterisierung des Prochamazulens Matrizin aus Matricaria chamomilla L.
Studies on the Characterization of the Chamazulene Precursor Matricine from Matricaria chamomilla L.
- The relative configuration of the thermolabile chamazulene precursor matricine has been established by NMR spectrometric studies. The NMR spectral data prove to be consistent with the well-known structure of the chamomile component. On the basis of our results the levorotatory natural substance moreover can be specified stereochemically as (−)-(3S*, 3aR*, 4S*, 9R*, 9aS*, 9bS*)-4-acetoxy-2,3,3a,4,5,9,9a,9b-octahydro-9-hydroxy-3,6,9-trimethylazuleno[4,5-b]furan-2-one.
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| Author: | Elmar FlaskampGND, Gottfried ZimmermannGND, Gerhard NonnenmacherGND, Otto Isaac |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719601 |
| DOI: | https://doi.org/10.1515/znb-1982-0420 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1982 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | Matricaria chamomilla L;; Matricine; NMR Spectra; Stereochemistry |
| Volume: | 37.1982 |
| Issue: | 4 |
| Page Number: | 4 |
| First Page: | 508 |
| Last Page: | 511 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| 5 Naturwissenschaften und Mathematik / 57 Biowissenschaften; Biologie / 570 Biowissenschaften; Biologie | |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
