Phasendiagramme und Exzeßvolumina der Systeme (CH3)2SiCl2/Pyridin und (CH3)2CCl2/Pyridin
Phase diagrams and excess volumes of the systems (CH3)2SiCl2/pyridine and (CH3)2CCl2/pyridine
- The isobaric melting and boiling diagrams for the systems: dimethyldichlorosilane/pyridine and 2,2-dichloropropane/pyridine are reproduced. The existence of the incongruently melting addition compounds (CH3)2SiCl2 · (Pyridine)2 and [(CH3)2CCl2]3 · Pyridine could be proved. Some measurements of the molar volume of mixtures of pyridine and dimethyldichlorosilane, and pyridine and 2,2-dichloropropane are reported. For both systems the molar excess volume has been calculated as a function of the mole fractions.
Author: | Michael W. Zenke, Karl Hensen |
---|---|
URN: | urn:nbn:de:hebis:30:3-815881 |
DOI: | https://doi.org/10.1515/znb-1994-0320 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1994 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/18 |
Tag: | 2-2-Dichloropropane; Dimethyldichlorosilane; Excess Volumes; Phase Diagrams; Pyridine |
Volume: | 49.1994 |
Issue: | 3 |
Page Number: | 5 |
First Page: | 412 |
Last Page: | 416 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |