Substituenteneffekte und Störung von π-Systemen, XXXV. Radikalanionen Zinn-substituierter Naphthaline
Substituent effects and perturbation of π systems, XXXV. Radical anions of tin-substituted naphthalenes
- Novel radical anions of trimethylstannyl substituted naphthalenes and their ESR spectra are reported. Both 119 Sn and 117 Sn coupling can be assigned unequivocally. The perturbation of π systems by R3X substituents of group IV b elements X = C, Si, Ge, Sn and Pb is discussed with respect to photoelectron ionization potentials, charge transfer excitations, half-wave reduction potentials and ESR spin distribution.
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| Author: | Hans BockGND, Wolfgang KaimORCiDGND, Holger TesmannGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719275 |
| DOI: | https://doi.org/10.1515/znb-1978-1104 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1978 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | ESR Spectra; Reduction to Radical Anions; Tin Organic Compounds; π Perturbation |
| Volume: | 33.1978 |
| Issue: | 11 |
| Page Number: | 4 |
| First Page: | 1223 |
| Last Page: | 1226 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
