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Thermodynamische Untersuchungen der Systeme Pyridin/CH3SiCl3 und Pyridin/Cl3CCH3

Thermodynamic Examinations of the Systems Pyridine/CH3SiCl3 and Pyridine/Cl3CCH3

  • The isobaric melting and boiling diagrams for the systems: pyridine/methyltrichlorosilane and pyridine/1,1,1-trichloroethane are reproduced. The existence of the congruently melting addition compound CH3SiCl3· (Pyridin)2 could be confirmed. Some measurements of the molar volume of mixtures between pyridine and methyltrichlorosilane and pyridine and 1,1,1-trichloroethane, respectively, are reported. For both systems the molar excess volume and for the system pyridine/methyltrichlorosilane the molar excess enthalpie have been calculated as a function of the mole fractions.

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Metadaten
Author:Michael W. Zenke, Karl Hensen
URN:urn:nbn:de:hebis:30:3-816381
DOI:https://doi.org/10.1515/znb-1993-0815
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1993
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2024/01/18
Volume:48.1993
Issue:8
Page Number:6
First Page:1127
Last Page:1132
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0