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Struktur des Addukts von Trimethylzinnchlorid Me3SnCl mit Trimethylzinnhydroxid Me3SnOH

Structure of the Adduct of Trimethyltin Chloride Me3SnCl with Trimethyltin Hydroxide Me3SnOH

  • Benzene solutions of Me3SnCl when exposed to moisture yield the adduct Me3SnCl·Me3SnOH·H2O. This adduct represents an intermediate in Me3SnCl hydrolysis. The structure of Me3SnCl·Me3SnOH·H2O features an array of Me3Sn units connected alternatingly by bridging Cl and OH ligands.

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Metadaten
Author:Hans-Wolfram LernerORCiDGND, Alireza Haghiri IlkhechiGND, Michael BolteORCiD, Matthias WagnerORCiD
URN:urn:nbn:de:hebis:30:3-698596
DOI:https://doi.org/10.1515/znb-2005-0410
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:2005
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/07/06
Tag:Hydrolysis; Trimethyltin Chloride; X-Ray Structure Analysis
Volume:60
Issue:4
Page Number:3
First Page:413
Last Page:415
HeBIS-PPN:511914350
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0