Thermolysereaktionen der donorfreien Silanimine tBu2Si=N-SiRtBu2 (R = tBu, Ph)
Thermolysis reactions of donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph)
- The donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph), which are prepared from tBu2ClSiN3 and NaSiRtBu2 at −78 ◦C inBu2O, decompose in benzene at room temperature with the formation of isobutene. Products of ene reactions of isobutene and tBu2Si=N-SiRtBu2 (R = tBu, Ph) are formed. X-Ray quality crystals of H2C=C(CH2SitBu2-NH-SiPhtBu2)2 (monoclinic, space group C2/c, Z = 4) were grown from a benzene solution at ambient temperature, whereas single crystals of H2C=C(CH2SitBu2-NH-SitBu3)2 (monoclinic, space group P21, Z = 2) were obtained by recrystallization from THF.
| Author: | Hans-Wolfram LernerORCiDGND, Inge Sänger, Michael BolteORCiD, Matthias WagnerORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-799738 |
| DOI: | https://doi.org/10.1515/znb-2010-0112 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 2010 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/26 |
| Tag: | Ene Reaction; SiN Double Bond; Silanimine; X-Ray Structure Analysis |
| Volume: | 65.2010 |
| Issue: | 1 |
| Page Number: | 7 |
| First Page: | 72 |
| Last Page: | 78 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
