2-Hydroxybenzyl alcohol–phenanthroline (1/1)
- Crystals of the title compound, C12H8N2·C7H8O2, were obtained during cocrystallization experiments of a compound with two hydrogen-bond donors (2-hydroxybenzyl alcohol) with another compound containing two hydrogen-bond acceptors (phenanthroline). Unexpectedly, the two molecules do not form dimers with two O—H ... N hydrogen bonds connecting the two molecules. However, one of the hydroxy groups forms a bifurcated hydrogen bond to both phenanthroline N atoms, whereas the other hydroxy group forms an O—H ... O hydrogen bond to a symmetry-equivalent 2-hydroxybenzyl alcohol molecule. In addition, the crystal packing is stabilized by Pi – Pi interactions between the two phenanthroline ring systems, with a centroid–centroid distance of 3.570 Å.
Verfasserangaben: | Ton Quoc Cuong, Michael BolteORCiD |
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URN: | urn:nbn:de:hebis:30-108545 |
DOI: | https://doi.org/10.1107/S1600536809044699 |
Titel des übergeordneten Werkes (Englisch): | Acta crystallographica / Section E, Structure reports online |
Dokumentart: | Wissenschaftlicher Artikel |
Sprache: | Englisch |
Jahr der Fertigstellung: | 2009 |
Jahr der Erstveröffentlichung: | 2009 |
Veröffentlichende Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Datum der Freischaltung: | 20.06.2011 |
Jahrgang: | 65 |
Ausgabe / Heft: | o2936 |
Bemerkung: | Copyright © Ton and Bolte 2009. This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
Quelle: | Acta Crystallographica Section E: Structure Reports Online, 65(Pt 11): o2936. ; doi: 10.1107/S1600536809044699 |
HeBIS-PPN: | 273357328 |
Institute: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
DDC-Klassifikation: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Lizenz (Deutsch): | Deutsches Urheberrecht |