Die Kristallstruktur von Bis(η-cyclopentadienyl)titana(Ti,IV)- cyclohexaselenan, Cp2TiSe5
The Crystal structure of Bis(η-cyclopentadienyl)titana(Ti,IV)- cyclohexaselenane, Cp2TiSe5
- Cp2TiSe5 has been prepared by the reaction of trim ethyltetradecylammonium-polyselenide with Cp2TiCl2 in ethanol solution and subsequent extraction of the dry residue with dichloromethane. Cp2TiSe5 crystallizes in the space group P1 with two formula units in the unit cell (2559 observed, independent reflexions, R = 0.074). The cell dimensions are a = 808.6, b = 822.6, c = 1190.7 pm, α - 96.28°, β - 106.06°, γ = 108.78°. The structure consists of discrete Cp2TiSe5 molecules with the TiSe5, ring in the chair conformation.
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| Author: | Dieter FenskeGND, Jörg Adel, Kurt DehnickeGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-799626 |
| DOI: | https://doi.org/10.1515/znb-1987-0724 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1987 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/12 |
| Tag: | Bis(η-cyclopentadienyl)titana(TiIV)cyclohexaselenane; Crystal Structure; Synthesis |
| Volume: | 42.1987 |
| Issue: | 4 |
| Page Number: | 3 |
| First Page: | 931 |
| Last Page: | 933 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
