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Remote and α-thio carbene complexes derived from an oxazolinylsubstituted thiophene
- Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.
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| Author: | Liliana Dobrzańska, Gerrit R. Julius, Elzet Stander-Grobler, Yolanda Burger, Stefan Dietrich NogaiGND, Stephanie CronjeORCiD, Helgard G. RaubenheimerORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-799794 |
| DOI: | https://doi.org/10.5560/znb.2012-0118 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 2012 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/26 |
| Tag: | Carbene Complexes; Chromium; Palladium; Thienylidene Complexes; remote Carbenes |
| Volume: | 67.2012 |
| Issue: | 6 |
| Page Number: | 10 |
| First Page: | 509 |
| Last Page: | 518 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
