Zur Reaktion von (η5-C5H5)Fe(CO)2Br mit Se(SiMe3)2. Die Kristallstruktur von [Se{Fe(CO)2(C5H5)}3]2[Fe4Se4Br4]
Reaction of (η5-C5H5)Fe(CO)2Br with SSe(SiMe3)2. The crystal structure of [Se{Fe(CO)2(C5H5)}3]2[Fe4Se4Br4]
- (η5-C5H5)Fe(CO)2Br reacts with Se(SiMe3)2 to form the title compound 1, which has been characterized by X-ray crystal structural analysis. 1 crystallizes in the space group P212121 with 4 formula units per unit cell. 1 consists of [Se{Fe(CO)2(C5H 5)}3]+- cations and [Fe4Se4Br4]2--anions, the latter with a heterocubane structure.
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| Author: | Dieter FenskeGND, Paul Georg Maué, Kurt MerzweilerORCiDGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-816652 |
| DOI: | https://doi.org/10.1515/znb-1987-0723 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1987 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/18 |
| Tag: | Crystal Structure of [Fe4Se4Br4]2--Cluster; Synthesis; X-Ray |
| Volume: | 42.1987 |
| Issue: | 7 |
| Page Number: | 3 |
| First Page: | 928 |
| Last Page: | 930 |
| Note: | Teil von Maué, Paul Georg: Neue Übergangsmetallkomplexe mit Chalkogenliganden. Frankfurt (Main), Univ., Diss., 1988 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
