Darstellung von monomerem Methylenaminoacetonitril H2C=N—CH2—CN in der Gasphase [1]
Preparation of monomerie methyleneaminoacetonitrile H2C=N—CH2—CN in the gas phase [1]
- The reactive intermediate methyleneaminoacetonitrile H2C = N - C H2 - CN has been generated via thermal retrotrimerization of N ,N',N"-tris(cyanomethyl)hexahydro-s-triazine and characterized by its photoelectron, mass and low-temperature NMR spectra. A fully geometryoptimized MNDO calculation allows to assign the observed ionization energies and yields estimates for other molecular properties, e.g. a rather high dipole moment.
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| Author: | Ralph DammelGND, Hans BockGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-799881 |
| DOI: | https://doi.org/10.1515/znb-1987-0702 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1987 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/11 |
| Tag: | 1H NMR Spectra; MNDO Calculations; Methyleneaminoacetonitrile Monomer and Trimer; PE Spectra; Thermal Retrotrimerization |
| Volume: | 42.1987 |
| Issue: | 7 |
| Page Number: | 5 |
| First Page: | 810 |
| Last Page: | 814 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
