N-(3-Bromophenyl)-3,4,5-trimethoxybenzamide

In the title compound, C16H16BrNO4, the dihedral between the planes of the aromatic rings is 7.74 (18)°. The amide group is tilted with respect to the bromo- and methoxy-substituted aromatic rings by 36.3 (8) and 35.2 (8)°, respectively. The meta-methoxy groups are essentially in-plane with the aromatic ring [dihedral angles CH3-O-C-C = -4.6 (4) and -2.5 (4)°]. The para-methoxy group is markedly displaced from the ring plane [dihedral angle CH3-O-C-C = -72.5 (4)°]. The crystal packing is stabilized by N-H...O hydrogen bonds linking the molecules into chains running along the b axis. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.004 Å; R factor = 0.033; wR factor = 0.076; data-to-parameter ratio = 14.6.

Metadaten
Author:	Aamer Saeed ORCiD, Shahid Hussain, Aliya Ibrar, Michael Bolte ORCiD
URN:	urn:nbn:de:hebis:30-69464
DOI:	https://doi.org/10.1107/S1600536809020509
Parent Title (English):	Acta crystallographica / Section E, Structure reports online
Document Type:	Article
Language:	English
Year of Completion:	2009
Year of first Publication:	2009
Publishing Institution:	Universitätsbibliothek Johann Christian Senckenberg
Release Date:	2009/09/09
Volume:	65
Issue:	o1470
Note:	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:	Acta Crystallographica Section E, Structure Reports Online, 2009, E65, o1470 ; doi:10.1107/S1600536809020509
HeBIS-PPN:	217658970
Institutes:	Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):	Creative Commons - Namensnennung 2.0

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