6,6'-Dimethyl-2,2'-[imidazolidine-1,3-diylbis(methylene)]diphenol
- In the title compound, C19H24N2O2, a di-Mannich base derived from 2-methylphenol and 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane, the imidazolidine ring adopts a twist conformation, with a twist about the ring N—C bond [C—N—C—C torsion angle = −44.34 (14)°]. The two 2-hydroxy-3-methylbenzyl groups are located in trans positions with respect to the imidazolidine fragment. The structure displays two intramolecular O—H⋯N hydrogen bonds, which each form an S(6) ring motif. In the crystal, the molecules are linked by weak C—H⋯O interactions with a bifurcated acceptor, forming a three-dimensional network.
| Author: | Augusto RiveraORCiD, Luz Stella Nerio, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-392898 |
| DOI: | https://doi.org/10.1107/S1600536814002128 |
| ISSN: | 1600-5368 |
| Parent Title (German): | Acta crystallographica. Section E, Structure reports online |
| Publisher: | International Union of Crystallography |
| Place of publication: | Chester |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/02/05 |
| Date of first Publication: | 2014/02/05 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2016/02/01 |
| Volume: | 70 |
| Issue: | o243 |
| Page Number: | 8 |
| Note: | This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| HeBIS-PPN: | 377893560 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 2.0 |
