On the order-disorder phase transformation of anilinium halides. III. High temperature phase crystal structure of anilinium bromide, C6H5NH3⊕Br⊖ : an X-ray and neutron diffraction study
- The crystal structure of the high temperature phase of anilinium bromide, C6H5NH3⊕Br⊖ , was studied by X-ray and neutron diffraction at T = 343 K. The refinement supports disordered positions of the -NH3⊕ group. A split-atom model is proposed which includes disorder of the benzene ring. The thermal parameters, hydrogen bond distances, and other experimental data (NMR, NQR, inelastic neutron scattering) are in accordance with this model.
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| Author: | Gerhard Fecher, Alarich WeissGND, Werner JoswigGND, Hartmut FueßGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-742486 |
| DOI: | https://doi.org/10.1515/zna-1981-0906 |
| ISSN: | 1865-7109 |
| Parent Title (German): | Zeitschrift für Naturforschung, A |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1981 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/06/27 |
| Volume: | 36 |
| Issue: | 9 |
| Page Number: | 11 |
| First Page: | 956 |
| Last Page: | 966 |
| HeBIS-PPN: | 510583148 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| 5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften | |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
