Reaktionen von Schwefel- und Phosphoramiden mit Trichlormethansulfenylchlorid

Reactions of sulfur- and phosphorus amides with trichloromethanesulfenyl chloride

  • Substituted amides react with tridiloromethanesulfenyl chloride in the presence of triethylamine to following compounds: S=PCl2NCH3SCCl3, S=PFCl2NCH3SCCl3, S =PFClNCH3SCCl3, S=PF2NCH3SCCl3, O = PCl2NCH3SCCl3, O= PFClNCH3SCCl3, O = PF2NCH3SCCl3, FSO2NCH3SCCl3 and CF3SO2-NCH3SCCl3. The properties of these substances are described. They were characteriszed by elemental analyses, IR- and mass spectra. 19F-, 1H- and 31P-NMR spectra are reported and discussed.

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Metadaten
Author:Herbert W. RoeskyORCiDGND, Wolfgang Schaper, Senol TutkunkardesGND
URN:urn:nbn:de:hebis:30:3-761030
DOI:https://doi.org/10.1515/znb-1972-0606
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1972
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/09/25
Volume:27
Issue:6
Page Number:6
First Page:620
Last Page:625
HeBIS-PPN:51311470X
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0