Reaktionskinetische Untersuchungenzur Bildung von Carbeniumionen des Triphenylmethyl-Typs
Kinetic investigations of the formation of carbenium ions of the triphenylm ethyl type
- The rates of formation of three mono- and three dicarbenium ions of the triphenylmethyl type from the corresponding carbinols in trifluoro acetic acid - toluene mixtures were investigated using stopped flow techniques. The reaction mechanisms are discussed in view of the obtained dependencies of the rate constants on acid concentration and temperature.
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| Author: | Matthias Walper, Hans-Dieter BrauerGND, Hartwig KelmGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-761422 |
| DOI: | https://doi.org/10.1515/znb-1975-7-818 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1975 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/09/25 |
| Tag: | carbenium ions; kinetics; triphenylmethyl ions |
| Volume: | 30 |
| Issue: | 7-8 |
| Page Number: | 5 |
| First Page: | 561 |
| Last Page: | 565 |
| HeBIS-PPN: | 513117024 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
