High-pressure/high-temperature synthesis of the new boron-rich terbium hydroxyborate Tb3B12O19(OH)7
- Monoclinic Tb3B12O19(OH)7 was obtained by multianvil high-pressure/high-temperature syntheses at 6 GPa and 650 °C. The crystal structure was investigated by single-crystal X-ray diffraction methods and space group C2 (no. 5) with the unit cell parameters a = 24.2299(5) Å, b = 4.4667(1) Å, c = 7.0964(2) Å, β = 94.58(1)°, and two formula units per cell were revealed. Powder X-ray diffraction, infrared spectroscopy and the investigation of its second harmonic generation properties support the proposed structural model.
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| Author: | Tobias A. TeichtmeisterORCiD, Lkhamsuren BayarjargalORCiDGND, Gunter HeymannORCiDGND, Hubert HuppertzORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-796896 |
| DOI: | https://doi.org/10.1016/j.solidstatesciences.2023.107373 |
| ISSN: | 1293-2558 |
| Parent Title (English): | Solid state sciences |
| Publisher: | Elsevier |
| Place of publication: | Amsterdam |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2023/11/21 |
| Date of first Publication: | 2023/11/16 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/11/22 |
| Tag: | Borate; Crystal structure; High-pressure; Solid-state chemistry; Terbium |
| Volume: | 146 |
| Issue: | 107373 |
| Article Number: | 107373 |
| Page Number: | 7 |
| HeBIS-PPN: | 515554758 |
| Institutes: | Geowissenschaften / Geographie / Geowissenschaften |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| 5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften | |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - CC BY-NC-ND - Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International |
