Mechanochemical synthesis of a cocrystal of two supramolecular hydrogen-bonded aggregates of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane (tatu) with 4-tert-butylphenol bearing different hydrogen bonding interactions
- The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.
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| Author: | Augusto RiveraORCiD, Jicli José Rojas, Jaime Ríos-MottaORCiD, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-535725 |
| DOI: | https://doi.org/10.3390/cryst8080309 |
| ISSN: | 2073-4352 |
| Parent Title (English): | Crystals |
| Publisher: | MDPI |
| Place of publication: | Basel |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2018/07/30 |
| Date of first Publication: | 2018/07/30 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2020/06/17 |
| Tag: | aminal structure; cocrystals; crystal engineering; hydrogen bonds; noncovalent interactions; supramolecular chemistry |
| Volume: | 8 |
| Issue: | 8, Art. 309 |
| Page Number: | 8 |
| First Page: | 1 |
| Last Page: | 8 |
| Note: | This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited |
| HeBIS-PPN: | 466838115 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 4.0 |
