Biphenyl-4,4'-diyl bis(2,2,5,5-tetramethyl-1-oxyl-3-pyrroline-3-carboxylate)

In the title compound, C30H34N2O6, the complete molecule is generated by a crystallographic 2/m symmetry operation. The 1-oxyl-3-pyrroline-3-carboxylate group lies on a mirror plane. The dihedral angle between the ring planes of the biphenyl fragment is constrained by symmetry to be zero, resulting in rather short intramolecular H...H contact distances of 2.02 Å. In the crystal, molecules are connected along the a-axis direction by very weak intermolecular methyl-phenyl C-H...[pi] interactions. The C-H bond is not directed to the center of the benzene ring, but mainly to one C atom [C-H...C(x - 1, y, z): H...C = 2.91 Å and C-H...C = 143°]. Key indicators: single-crystal X-ray study; T = 169 K; mean σC–C) = 0.002 Å ; R factor = 0.049; wR factor = 0.126; data-to-parameter ratio = 19.8.

Metadaten
Author:	Dominik Margraf, Denise Schütz, Thomas F. Prisner ORCiD, Jan W. Bats
URN:	urn:nbn:de:hebis:30-68977
DOI:	https://doi.org/10.1107/S1600536809024659
Parent Title (English):	Acta crystallographica / Section E, Structure reports online
Document Type:	Article
Language:	English
Year of Completion:	2009
Year of first Publication:	2009
Publishing Institution:	Universitätsbibliothek Johann Christian Senckenberg
Release Date:	2009/09/04
Volume:	65
Issue:	o1784
Note:	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:	Acta Crystallographica Section E, Structure Reports Online, 2009. E65, o1784 doi:10.1107/S1600536809024659
HeBIS-PPN:	217331130
Institutes:	Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):	Creative Commons - Namensnennung 2.0

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