Bis{μ-[(di­phenyl­phosphor­yl)meth­yl]-(phen­yl)bis­­(1H-pyrazol-1-yl)boranuido}-dilithium

The title compound, [Li2(C25H23BN4OP)2], features a centrosymmetric dimeric complex. The four-memberered Li2O2 ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of 
The title compound, [Li2(C25H23BN4OP)2], features a centrosymmetric dimeric complex. The four-memberered Li2O2 ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of two different pyrazole rings. The dihedral angle between two pyrazole rings bonded to the same B atom is 45.66 (9)°. The B—N—N—Li—N—N metalla ring adopts a boat conformation. The crystal packing is stabilized by van der Waals inter­actions only.
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Author:Manuela Müller, Hans-Wolfram Lerner, Michael Bolte
URN:urn:nbn:de:hebis:30:3-392857
DOI:http://dx.doi.org/10.1107/S1600536814011945
ISSN:1600-5368
Parent Title (German):Acta crystallographica. Section E, Structure reports online
Publisher:International Union of Crystallography
Place of publication:Chester
Document Type:Article
Language:English
Date of Publication (online):2014/05/31
Date of first Publication:2014/05/31
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2016/02/01
Volume:70
Issue:m237
Pagenumber:11
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
HeBIS PPN:377816035
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 2.0

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