6,6'-Di­methyl-2,2'-[imidazolidine-1,3-diyl­bis­(methyl­ene)]diphenol

In the title compound, C19H24N2O2, a di-Mannich base derived from 2-methyl­phenol and 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]dodecane, the imidazolidine ring adopts a twist conformation, with a twist about the ring N—C 
In the title compound, C19H24N2O2, a di-Mannich base derived from 2-methyl­phenol and 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]dodecane, the imidazolidine ring adopts a twist conformation, with a twist about the ring N—C bond [C—N—C—C torsion angle = −44.34 (14)°]. The two 2-hy­droxy-3-methyl­benzyl groups are located in trans positions with respect to the imidazolidine fragment. The structure displays two intra­molecular O—H⋯N hydrogen bonds, which each form an S(6) ring motif. In the crystal, the mol­ecules are linked by weak C—H⋯O inter­actions with a bifurcated acceptor, forming a three-dimensional network.
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Metadaten
Author:Augusto Rivera, Luz Stella Nerio, Michael Bolte
URN:urn:nbn:de:hebis:30:3-392898
DOI:http://dx.doi.org/10.1107/S1600536814002128
ISSN:1600-5368
Parent Title (German):Acta crystallographica. Section E, Structure reports online
Publisher:International Union of Crystallography
Place of publication:Chester
Document Type:Article
Language:English
Date of Publication (online):2014/02/05
Date of first Publication:2014/02/05
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2016/02/01
Volume:70
Issue:o243
Pagenumber:8
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
HeBIS PPN:377893560
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 2.0

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