Isocyanate und Isothiocyanate von cyclischen Phosphor-Stickstoff-Verbindungen

Isocyanates and isothiocyanates of cyclic phosphorus nitrogen compounds

  • By substitution of a halogen atom in cyclic phosphazenes by isocyanate or isothiocyanate new members of this class of compounds are synthesized. These compounds are fairly stable against hydrolysis. Reaction of the new compounds with amines yields P3N3F5NHC(O)N(CH3)2 and P3N3F5NHC(S)N(CH3)2. With elemental chlorine P3N3F5N = CCl2 is formed. Numerous IR, NMR and mass spectra data of the new compounds are reported.

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Metadaten
Author:Herbert W. RoeskyORCiDGND, Enno JanßenGND
URN:urn:nbn:de:hebis:30:3-761281
DOI:https://doi.org/10.1515/znb-1974-3-408
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1974
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/09/22
Tag:isocyanate; isothiocyanate; phosphorus
Volume:29
Issue:3-4
Page Number:3
First Page:174
Last Page:176
HeBIS-PPN:513116540
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0