Bis{μ-[(diphenylphosphoryl)methyl]-(phenyl)bis(1H-pyrazol-1-yl)boranuido}-dilithium
- The title compound, [Li2(C25H23BN4OP)2], features a centrosymmetric dimeric complex. The four-memberered Li2O2 ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of two different pyrazole rings. The dihedral angle between two pyrazole rings bonded to the same B atom is 45.66 (9)°. The B—N—N—Li—N—N metalla ring adopts a boat conformation. The crystal packing is stabilized by van der Waals interactions only.
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| Author: | Manuela Müller, Hans-Wolfram LernerORCiDGND, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-392857 |
| DOI: | https://doi.org/10.1107/S1600536814011945 |
| ISSN: | 1600-5368 |
| Parent Title (German): | Acta crystallographica. Section E, Structure reports online |
| Publisher: | International Union of Crystallography |
| Place of publication: | Chester |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/05/31 |
| Date of first Publication: | 2014/05/31 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2016/02/01 |
| Volume: | 70 |
| Issue: | m237 |
| Page Number: | 11 |
| Note: | This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| HeBIS-PPN: | 377816035 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 2.0 |
