TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Ambrosius, Klaus
T1  - Über Reaktionen von 3-trifluormethylphenylsubstituierten silicium-und zinnorganischen Verbindungen
T1  - Reactions of 3-trifluoromethylphenyl substituted silicon and tin organic compounds
T2  - Zeitschrift für Naturforschung, B
N2  - Several routes were investigated for the preparation of 3-CF3C6H4N[Si(CH3)3]2 2 and 3-CF3C6H4N[Sn(CH3)3]2 3. The latter compound reacts with 3-CF3C6H4NCO to yield [3-CF3C6H4(CH3)3SnN]2CO 4. A substituted urea 5 is also formed from [(CH3)3Si]2NCH3 and 3-CF3C6H4NCO. 5 is used for the preparation of cyclic compounds, with S2Cl2 the ten-membered ring (3-CF3C6H4NCONCH3S2)2 6 is formed. 5 and HN(SO2Cl)2 yield the six-membered ring 3-CF3C6H4NCONCH3(SO2)2NH 7. SeOCl2 and 5 react under formation of a spiro compound (S-CF3C6H4NCONCH3)2Se 8. The compounds were characterized on the basis of mass and 19F NMR spectra.
KW  - Fluoro Compounds
KW  - Cycles
KW  - Silicon
KW  - Tin
KW  - Metal Organic Derivatives
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71918
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719188
SN  - 1865-7117
SN  - 0932-0776
VL  - 33.1978
IS  - 7
SP  - 759
EP  - 762
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -