TY  - JOUR
A1  - Tillmann, Jan
A1  - Lerner, Hans-Wolfram
A1  - Bolte, Michael
T1  - A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl3)4·C6H6
T2  - Acta crystallographica. Section E, Crystallographic communications
N2  - A new pseudopolymorph of dodeca­chloro­penta­silane, namely a benzene monosolvate, Si5Cl12·C6H6, is described. There are two half mol­ecules of each kind in the asymmetric unit. Both Si5Cl12 mol­ecules are completed by crystallographic twofold symmetry. One of the benzene mol­ecules is located on a twofold rotation axis with two C—H groups located on this rotation axis. The second benzene mol­ecule has all atoms on a general position: it is disordered over two equally occupied orientations. No directional inter­actions beyond normal van der Waals contacts occur in the crystal.
KW  - crystal structure
KW  - co-crystal
KW  - polymorphism
KW  - solvate
Y1  - 2020
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/54302
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-543025
SN  - 2056-9890
N1  - This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
VL  - 76
IS  - 2
SP  - 261
EP  - 263
PB  - International Union of Crystallography ; National Center for Biotechnology Information, U.S. National Library of Medicine
CY  - Chester ; Bethesda, MD
ER  -