TY - JOUR A1 - Dammel, Ralph A1 - Bock, Hans T1 - Darstellung von monomerem Methylenaminoacetonitril H2C=N—CH2—CN in der Gasphase [1] T1 - Preparation of monomerie methyleneaminoacetonitrile H2C=N—CH2—CN in the gas phase [1] T2 - Zeitschrift für Naturforschung, B N2 - The reactive intermediate methyleneaminoacetonitrile H2C = N - C H2 - CN has been generated via thermal retrotrimerization of N ,N',N"-tris(cyanomethyl)hexahydro-s-triazine and characterized by its photoelectron, mass and low-temperature NMR spectra. A fully geometryoptimized MNDO calculation allows to assign the observed ionization energies and yields estimates for other molecular properties, e.g. a rather high dipole moment. KW - Methyleneaminoacetonitrile Monomer and Trimer KW - Thermal Retrotrimerization KW - PE Spectra KW - MNDO Calculations KW - 1H NMR Spectra Y1 - 2014 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79988 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799881 SN - 1865-7117 SN - 0932-0776 VL - 42.1987 IS - 7 SP - 810 EP - 814 PB - Verlag der Zeitschrift für Naturforschung CY - Tübingen ER -