TY  - JOUR
A1  - Merzweiler, Kurt
A1  - Fenske, Dieter
A1  - Hartmann, Eva
A1  - Dehnicke, Kurt
T1  - Synthese und Kristallstruktur des Imidokomplexes {TaCl4NC(Ph)[N(SiMe3)2]}2·2 CH2Cl2
T1  - Synthesis and crystal structure of the imido complex {TaCl4NC(Ph)[N(SiMe3)2]}2·2 CH2Cl2
T2  - Zeitschrift für Naturforschung, B
N2  - The title compound has been prepared by the reaction of N,N,N′-tris(trimethylsilyl)benzamidine with tantalum pentachloride in CH2Cl2 suspension, forming amber-coloured, moisturesensitive crystals, which were characterized by an X-ray structure determination. Space group P 21/n, Z = 2, 4895 observed independent reflexions, R = 0.059. Lattice dimensions (-65°C): a = 1165.2(6), b = 1335.4(6), c = 1629.0(7) pm, β = 93.23(4)°. The complex forms centrosymmetric molecules dimerized via chloro bridges TaCl2Ta with TaCl bond lengths of 247.2(2) and 277.1(2) pm, the longer one being in trans-position to the imido group, which can be formulated as [xxx] (bond lengths Ta=Ν = 183.5(8), C=N = 134(1) pm, bond angle TaNC = 162.7(7)°).
KW  - Imido Complex of Tantalum
KW  - Synthesis
KW  - IR Spectra
KW  - Crystal Structure
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/80930
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-809302
SN  - 1865-7117
SN  - 0932-0776
VL  - 44.1989
IS  - 9
SP  - 1003
EP  - 1006
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -