TY  - JOUR
A1  - Bock, Hans
A1  - Chenard, Bertrand Leo
A1  - Rittmeyer, Peter
A1  - Stein, Udo C.
T1  - Radical ions, 78 [1, 2]. The oxidative desulfuration of organic cyclic polysulfides to disulfide radical cations in AlCl3/H2CCl2 solution
T2  - Zeitschrift für Naturforschung, B
N2  - Organodisulfide radical cations R2S2′⊕ and R2C2S2 ′⊕ can be generated from aliphatic as well as aromatic cyclic polysulfides in AlCl3/H2CCl2 solutions and characterized by their ESR spectra. Examples presented are the oxidations of 1,2,3-trithiolanes to 1.2-dithiolane radical cations, in which energetically favored planarized 3 electron/2 center bonds  are formed.
KW  - Cyclic Organosulfides
KW  - One-Electron Oxidation
KW  - ESR Spectra
KW  - Structural and Conformational Changes
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71431
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-714311
SN  - 1865-7117
SN  - 0932-0776
VL  - 43.1988
IS  - 1
SP  - 117
EP  - 124
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -