TY  - JOUR
A1  - Bock, Hans
A1  - Hauck, Tim
A1  - Näther, Christian
A1  - Havlas, Zdenek
T1  - Wechselwirkungen in Kristallen, 35 [1, 2]. Einkristallzüchtung von Na⊕⊖C(NO2)3 [***] aus Etherlösungen zu einem polymeren Band [(Na⊕⊖C(NO2)3) Dioxan]∞ und einem Lösungsmittel-getrennten Ionenpaar [(Na⊕/18-Krone-6)(THF)2]⊕[(Na⊕/18-Krone-6)(ONO-C⊖(NO2)2)2]⊖
T1  - Interactions in Crystals, 35 [1, 2]. Single Crystal Growths of Na⊕⊖C(NO2)3[***] from Ether Solutions to a Polymer Band [(Na⊕⊖C(NO2)3)Dioxane]∞ and to a Solvent-Separated Ion Pair [(Na⊕/18-Crown-6)(THF)2]⊕[(Na⊕/18-Crown-6)(ONO-C⊖(NO2)2)2]⊖
T2  - Zeitschrift für Naturforschung, B
N2  - The sodium salt of the most simple polynitro-substituted hydrocarbon anion. Na⊕⊖C(NO2)3, (for a hazard warning cf. [***]) crystallizes from ether solutions without and with addition of 18-crown-6 either in a polymer band. [(Na⊕⊖C(NO2)3)dioxane]∞, or as a solvent- separated ion pair, [(Na⊕/18-crown-6)(THF2]⊕[(Na⊕/18-crown-6)(O2N-C⊖(NO2)2)2]⊖. The Na⊕ cations are each 8-fold coordinated in hexagonal bipyramidal arrangement. According to extensive quantum-chemical calculations based on the structure coordinates, the formation of these novel salts can be traced back to the charge distribution in the anions ⊖C(NO2)3. which due to negatively charged oxygen centers are favorable complex ligands. The structure determining effects of solvation are discussed.
KW  - Single Crystal Structure
KW  - MNDO Calculations
KW  - Solvation Effects
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/81667
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-816673
SN  - 1865-7117
SN  - 0932-0776
VL  - 49.1994
IS  - 8
SP  - 112
EP  - 120
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -