TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Zamankhan, Hamid
T1  - Zur Synthese von phosphorhaltigen Heterocyclen mit metallorganischen Verbindungen
T1  - Synthesis of phosphorus containing heterocycles with metal organic compounds
T2  - Zeitschrift für Naturforschung, B
N2  - CH3P(S)(NCO)2 reacts with [(CH3)3Si]2N-CH3, [(CH3)3SiNCH3]2CO and [(CH3)3Sn]3N to give the cyclic compounds 2a-2c. The structures are discussed on the basis of NMR and IR data. In 2 a and 2 b the (CH3)3Si-groups are easily and quantitatively replaced by protons with water under formation of (CH3)3Si-O-Si(CH3)3. By the reaction of CH3P(S)(NCO)2 with [(CH3)3Si]2S 4 is obtained, a cyclic compound with a sulfur atom of coordination number 2.
FP(S)(NCS)2 was used to investigate the scope of these reactions. With [(CH3)3Si]2NCH3 and FP(S)(NCS)2 5 is obtained, which reacts with S2Cl2 to yield 6, a bridged disulfur compound. This method may be useful for the systematic investigation of new cyclic compounds.
KW  - Cyclic Compounds
KW  - Phosphorus
KW  - Metal Organic Derivates
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76906
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-769060
SN  - 1865-7117
SN  - 0932-0776
VL  - 32
IS  - 2
SP  - 229
EP  - 233
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -