TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Schmieder, Wilfried
A1  - Ambrosius, Klaus
T1  - Über Additionsreaktionen von zinnorganischen Verbindungen mit N.N′-Bis(pentafluorphenyl)-schwefeldiimid
T1  - Addition reactions of tinorganic compounds with N,N′-Bis(pentafluorophenyl)sulfurdiimide
T2  - Zeitschrift für Naturforschung, B
N2  - The reactions of N,N′ -bis(pentafluorophenyl)sulfurdiimide with [(CH3)3Sn]2NCH3, [(CH3)3Sn]3N and [(CH3)3Sn]2NC6F5 yiels the 1:1 adducts 1-3. 1H and 19 F NMR investigations show, that fluorine atoms in the ortho position of the phenyl ring coordinate to the tin atom. This causes an increase of electron density at tin. A similar interpretation is given for the adduct 4 of N,N′-bis(p-chlorophenylsulfonyl)sulfurdiimide and [(CH3)3Sn]2NCH3, where an oxygen atom of the sulfonyl group is bonded to tin.
KW  - Pentafluorophenyl Derivatives
KW  - Tin
KW  - Coordination Compounds
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71931
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719315
SN  - 1865-7117
SN  - 0932-0776
VL  - 34.1979
IS  - 2
SP  - 197
EP  - 199
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -